01What is postacert.eml?
It is the envelope the certified mail system builds around your message. A PEC provider does not deliver the original email to you directly: it wraps it, together with its attachments and the delivery receipts, inside a new message, and that inner original travels as an attachment called postacert.eml. So the file you are looking at is a complete email in itself, which is why a normal double click either opens it in the wrong program or shows you a message with no attachments. What you want is inside it.
03Why does opening a PEC attachment normally take four steps?
Because each tool works on files, and files live on disk. You download the postacert.eml, open it somewhere to save the .p7m, download that, then load it into something that unwraps signatures. Two of those four actions exist only to move bytes between two programs. Here both tools run in the same browser tab, so the output of the first is already in memory when the second starts: you drop once and download once.
07Can I open the postacert.eml without this page?
Yes, with a desktop mail client that lets you save attachments out of an attached message, plus signature software for the .p7m. That is the four-step route, and it needs both programs installed. This page exists because the two operations are the same two operations every time, and a browser can do both.